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Key areas - interdisciplinary task groups
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In order to intensify both the interdisciplinary and international colaboration work
within the EGS we decided to group the running research projects according to the following topics:
Fundamentals
Heterogeneous Systems
Controlled Polymerization
Materials
One day of the semi-annually hold workshop was dedicated to team work, that is, the latest results of
the ongoing projects were presented and discussed in the respective task groups. In addition, extensions
for running collaborations and future projects were projected. The broad range of experimental expertise
of the task group members on synthesis and characterization of polymeric materials has proven to be
extremely advantageous for supporting each other´s work by stimulating new ideas and helping with unsettled
problems. These task groups were the starting point for the development of new syntheses and analytical
techniques as well as tailored simulation program packages, which were commonly explored and used by the
individual research groups and exploited for the particular research efforts. The various experimental
resources within the EGS were made available to the members in an easy and straight-forward manner in
order to allow quick access. Travel costs were covered by the DFG and NWO, respectively. The success of
our interdisciplinary task groups is demonstrated by an increasing number of joint publications, either
being published or in preparation. Involving junior researchers in the ongoing jointly performed projects
teaches scientific diversity, interdisciplinary research and teamwork to the undergraduates in an
early stage of their education.
The four key areas, which are coordinated by one or two academics, are outlined below:
Fundamentals
Coordinator: S. Beuermann (Göttingen)
The availability of reliable rate coefficients of radical polymerization for wide
ranges of temperature and pressure, respectively, is of immanent importance for the
detailed understanding of the individual reaction steps of homo- and copolymerization.
In addition, knowledge about these rate coefficients is vital for modeling and understanding
of solvent effects.
Heterogeneous Systems
Coordinator: A.M. van Herk (Eindhoven)
Kinetic aspects of emulsion polymerization of homo-, co-, and terpolymers as well as impact of
polymerization conditions, initiator and emulsifier on microstructure and particle size are
highly relevant for improving this economically important polymerization technique.
Controlled Polymerization
Coordinator: P. Vana (Göttingen), M. Drache (Clausthal)
Various controlled radical polymerization techniques are currently available for the controlled
synthesis of complex macromolecular architectures, such as block, comb, and star polymers. The most
prominent of these methods are SFRP (stable free radical polymerization), ATRP (atom transfer radical
polymerization) and RAFT (reversible addition fragmentation chain transfer polymerization).
The complete kinetic scheme of the RAFT polymerization is still under discussion in the scientific
community and is tried being elucidated via dedicated experimental approaches, supported by modeling
procedures for which advanced and more effective simulation modules are required.
Materials
Coordinator: W. Oppermann ( Clausthal)
Grafting methods in conjunction with cross-linking processes in polymer solution or on solid surfaces
allow for the generation of complex polymeric structures. For obtaining these structures, a multitude
of different polymerization techniques (e.g., conventional radical, living radical, cationic) may
either be employed alone or used in various combinations.